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General Shop Safety - Hazardous Materials Safety
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Federal law dictates that employers must provide information to their employees about hazardous materials and chemicals that employees may be exposed to in the workplace. The vehicle for that information is the Material Safety Data Sheet (MSDS). While there is no specified format for the MSDS, OSHA has developed a non-mandatory format, OSHA Form 174, which may be used by chemical manufacturers and importers to comply with OSHA's Hazard Communication Standard.

You are entitled to receive a data sheet from your supplier. Figure 5 shows a blank OSHA Form 174 that shows you what kind of materials you are working with regarding the chemical make-up, including the identity, characteristics, and hazard data.

Figure 5 Below. Example of a typical MSDS sheet

Material Safety Data Sheet

U.S. Department of Labor

May be used to comply with OSHA’s Hazard Communication Standard, 29 CFR 1910 1200. Standard must be consulted for specific requirements.

Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072

IDENTITY (as Used on Label and List)

Note: Blank spaces are not permitted. If any item is not
applicable or no information is available, the space
must be marked to indicate that.

Section I

Manufacturer’s name

Emergency Telephone Number

Address (Number, Street, City, State and ZIP Code)

Telephone Number for Information

 

Date Prepared

 

Signature of Preparer (optional)

Section II—Hazardous Ingredients/Identity Information

Hazardous Components (Specific Chemical Identity, Common Name(s))


OSHA PEL


ACGIH TLV

Other Limits Recommended


% (optional)

 
 
 
 
 

Section III—Physical/Chemical Characteristics

Boiling Point

 

Specific Gravity (H20 = 1)

 

Vapor Pressure (mm Hg)

 

Melting Point

 

Vapor Density (AIR = 1)

 

Evaporation Rate (Butyl Acetate = 1)

 

Solubility in Water

Appearance and Odor

Section IV—Fire and Explosion Hazard Data

Flash Point (Method Used)

Flammable Limits

LEL

UEL

Extinguishing Media

Special Fire Fighting Procedures

 

Unusual Fire and Explosion Hazards

 

(Reproduce locally) OSHA 174 Sept. 1985

 Section V—Reactivity Data

Stability

Unstable

 

Conditions to Avoid

 

Stable

   

Incompatibility (Materials to Avoid)

Hazardous Decomposition or Byproducts

Hazardous
Polymerization

May Occur

 

Conditions to Avoid

 

Will Not Occur

   

Section VI—Health Hazard Data

Route(s) of Entry

Inhalation?

Skin?

Ingestion?

Health Hazards (Acute and Chronic)

 
 

Carcinogenicity

NTP?

IARC Monographs?

OSHA Regulated?

 

Signs and Symptoms of Exposure

 

Medical Conditions
Generally Aggravated by Exposure

 

Emergency and First Aid Procedures

 

Section VII—Precautions for Safe Handling and Use

Steps to Be Taken in Case Material Is Released or Spilled

 
 

Waste Disposal Method

 

Precautions to Be Taken in Handling and Storing

 

Other Precautions

 

Section VII—Control Measures

Respiratory Protection (Specify Type)

Ventilation

Local Exhaust

Special

 

Mechanical (General)

Other

Protective Gloves

Eye Protection

Other Protective Clothing or Equipment

Work/Hygienic Practices

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